Non-LTE analysis for Helium and Strontium lines in the kilonova AT2017gfo

Kilonova spectra imprint valuable information about the elements synthesized in neutron star mergers. In AT2017gfo, the kilonova associated with GW170817, the spectroscopic feature centered around 8000 angstroms has been interpreted as the P-Cygni profile arising from singly ionized Strontium. Recently, Perego et al. (2022) suggested that Helium 10833 line can be an alternative explanation of the feature. Here, we study the line features under non-local thermodynamic equilibrium. We find that the ionization of ejecta by the stopping of radioactive decay product can significantly enhance the ionization states around the line forming region. We compute the kilonova spectrum under the assumption of spherical symmetry and uniform elemental fraction in the line-forming region. We find that 0.2\% (in mass) of Helium in the ejecta can reproduce the P-Cygni feature in the observed spectrum at $1.43$ -- $4.40$ days. Strontium with a mass fraction of $1\%$ is also able to make the absorption feature at $\sim 1.5\,$days, but it gets weaker with time due to ionization by radioactive decay products. The strength of the He line signature depends sensitively on UV strength for the first two epochs. Further modeling of UV line blanketing by $r$-process elements and the optical properties of light $r$-process elements would be crucial to distinguish between Helium and Strontium features. The mass fraction of He is a good indicator for ejecta entropy that allows us to probe the mass ejection mechanism.