Diversity of early kilonova with the realistic opacities of highly ionized heavy elements

We investigate the early (t < 1 day) kilonova from the neutron star merger by deriving atomic opacities for all the elements from La to Ra (Z = 57 - 88) ionized to the states V - XI. The opacities at high temperatures for the elements with open f-shells (e.g., lanthanides) are exceptionally high, reaching kappa_{exp} ~ 10^4 cm2/g at lambda < 1000 A at T ~ 70,000 K, whereas, the opacities at the same temperature and wavelengths for the elements with the open d-, p-, and s-shells reach kappa_{exp} ~ 1 cm2/g, 0.1 cm2/g, and 0.01 cm2/g, respectively. Using the new opacity dataset, we derive the early kilonovae for various compositions and density structures expected for neutron star merger ejecta. The bolometric luminosity for the lanthanide-rich ejecta shows distinct signatures and is fainter than that for the lanthanide-free ejecta. The early luminosity is suppressed by the presence of a thin outer layer, agreeing with the results of Kasen et al. (2017) and Banerjee et al. (2020). The early brightness in Swift UVOT filters and in the optical g-, r-, i-, z-filters for a source at 100 Mpc are ~ 22 - 20 mag and ~ 21 - 19 mag, respectively, at t ~ 0.1 days. Such kilonovae are ideal targets for the upcoming UV satellites, such as ULTRASAT, UVEX, and DORADO, and the upcoming surveys, e.g., Vera Rubin Observatory. We suggest the gray opacities to reproduce the bolometric light curves with and without lanthanides are ~ 1 - 20 cm2/g and ~ 0.8 - 1 cm2/g.