Physical and chemical complexity in high-mass star-forming regions with ALMA. I. Overview and evolutionary trends of physical properties

In this study, we investigate how physical properties, such as the density and temperature profiles, evolve on core scales through the evolutionary sequence during high-mass star formation ranging from protostars in cold infrared dark clouds to evolved UCHII regions. We observed 11 high-mass star-forming regions with ALMA at 3 mm wavelengths. Based on the 3 mm continuum morphology and recombination line emission, tracing locations with free-free (ff) emission, the fragmented cores analyzed in this study are classified into either dust or dust+ff cores. In addition, we resolve three cometary UCHII regions with extended 3 mm emission that is dominated by free-free emission. The temperature structure and radial profiles (T~r^-q ) are determined by modeling molecular emission of CH3CN and CH313CN with XCLASS and by using the HCN-to- HNC intensity ratio as probes for the gas kinetic temperature. The density profiles (n~r^-p ) are estimated from the 3 mm continuum visibility profiles. The masses M and H2 column densities N(H2) are then calculated from the 3 mm dust continuum emission. Results. We find a large spread in mass and peak H2 column density in the detected sources ranging from 0.1-150 Msun and 10^23 - 10^26 cm-2 , respectively. Including the results of the CORE and CORE-extension studies (Gieser et al. 2021, 2022) to increase the sample size, we find evolutionary trends on core scales for the temperature power-~law index q increasing from 0.1 to 0.7 from infrared dark clouds to UCHII regions, while for the the density power-law index p on core scales, we do not find strong evidence for an evolutionary trend. However, we find that on the larger clump scales throughout these evolutionary phases the density profile flattens from p = 2.2 to p = 1.2. (abridged)