pith. sign in

arxiv: 1906.12022 · v1 · pith:4YJCJC3Rnew · submitted 2019-06-28 · ❄️ cond-mat.str-el

Crossover from charge density wave stabilized antiferromagnetism to superconductivity in Nd_(1-x)La_xNiC₂ compounds

Pith reviewed 2026-05-25 14:14 UTC · model grok-4.3

classification ❄️ cond-mat.str-el
keywords charge density waveantiferromagnetismsuperconductivitydopingPeierls transitionquantum critical pointNdNiC2LaNiC2
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0 comments X

The pith

La substitution suppresses the charge density wave in NdNiC2 at xc=0.38, after which antiferromagnetism softens and superconductivity appears once the magnetic transition reaches zero temperature.

A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.

The paper tracks the evolution of Nd1-xLaxNiC2 as La replaces Nd. The Peierls temperature of the charge density wave falls with doping and vanishes at xc=0.38 according to a BCS mean-field relation for chemical pressure. While the charge density wave persists the antiferromagnetic transition stays sharp despite a falling Néel temperature. Once the charge density wave is eliminated the antiferromagnetic features broaden, spin disorder rises, and superconductivity emerges immediately after the antiferromagnetic transition temperature reaches zero. The sequence is interpreted as evidence for a possible quantum critical point.

Core claim

In the Nd1-xLaxNiC2 series the charge density wave is suppressed at xc=0.38 following the BCS mean-field relation for chemical pressure. As long as the charge density wave is maintained the antiferromagnetic ground state remains robust with a rapid and sharp magnetic transition. Once the charge density wave is completely suppressed the antiferromagnetic features soften with increasing spin disorder. Superconductivity appears immediately after the antiferromagnetic transition is depressed to zero temperature.

What carries the argument

La substitution acting as chemical pressure that tunes the Peierls temperature, drives CDW suppression at xc=0.38, and produces the crossover from CDW-stabilized antiferromagnetism to superconductivity.

If this is right

  • The antiferromagnetic ground state stays robust with a sharp transition while the charge density wave is present.
  • Complete removal of the charge density wave causes gradual softening of antiferromagnetic features and growth of spin disorder.
  • Superconductivity appears as soon as the antiferromagnetic transition temperature reaches zero.
  • The doping-driven sequence is consistent with a possible quantum critical point between the antiferromagnetic and superconducting states.

Where Pith is reading between the lines

These are editorial extensions of the paper, not claims the author makes directly.

  • The noncentrosymmetric structure inherited from LaNiC2 may allow tests for mixed-parity pairing in the superconducting state of the doped compounds.
  • Comparison of the chemical-pressure tuning here with hydrostatic-pressure experiments on pure NdNiC2 could check whether the same critical point is reached by both routes.
  • Signatures of non-Fermi-liquid behavior or enhanced fluctuations near the point where the antiferromagnetic transition vanishes would support the quantum-critical interpretation.

Load-bearing premise

The observed suppression of the Peierls temperature with La substitution follows the BCS mean-field relation for chemical pressure, fixing xc=0.38 as the point where the charge density wave vanishes.

What would settle it

A measurement showing a finite charge density wave transition temperature persisting at x=0.38, or a sharp antiferromagnetic transition continuing at higher La concentrations without the reported softening, would falsify the critical concentration and crossover sequence.

Figures

Figures reproduced from arXiv: 1906.12022 by Kamil K. Kolincio, Leszek Litzbarski, Marta Roman, Tomasz Klimczuk.

Figure 1
Figure 1. Figure 1: FIG. 1. a) Normalized pXRD patterns for selected samples fro [PITH_FULL_IMAGE:figures/full_fig_p003_1.png] view at source ↗
Figure 2
Figure 2. Figure 2: FIG. 2. a) Temperature dependence of the molar magnetic susc [PITH_FULL_IMAGE:figures/full_fig_p004_2.png] view at source ↗
Figure 3
Figure 3. Figure 3: FIG. 3. a) The real part of the molar magnetization [PITH_FULL_IMAGE:figures/full_fig_p005_3.png] view at source ↗
Figure 4
Figure 4. Figure 4: FIG. 4. a) The thermal dependence of the normalized electric [PITH_FULL_IMAGE:figures/full_fig_p006_4.png] view at source ↗
Figure 5
Figure 5. Figure 5: FIG. 5. The thermal variation of the normalized electrical r [PITH_FULL_IMAGE:figures/full_fig_p007_5.png] view at source ↗
Figure 6
Figure 6. Figure 6: FIG. 6. Phase diagram of temperature vs. composition [PITH_FULL_IMAGE:figures/full_fig_p008_6.png] view at source ↗
read the original abstract

The path from the charge density wave antiferromagnet NdNiC$_2$ to a noncentrosymmetric superconductor LaNiC$_2$ has been studied by gradual replacement of Nd by La ions. The evolution of physical properties has been explored by structural, magnetic, transport, magnetoresistance and specific heat measurements. With the substitution of La for Nd, the Peierls temperature is gradually suppressed, which falls within the BCS mean-field relation for chemical pressure with a critical concentration of $x_c$ = 0.38. As long as charge density wave is maintained, the antiferromagnetic ground state remains robust against doping and despite of a N\'eel temperature reduction shows a rapid and sharp magnetic transition. Once the CDW is completely suppressed, intermediate compounds of the Nd$_{1-x}$La$_x$NiC$_2$ series reveal symptoms of a gradual softening of the features associated with AFM transition and increase of the spin disorder. Immediately after the antiferromagnetic transition is depressed to zero temperature, the further incorporation of La ions results in the emergence of superconductivity. This crossover in the Nd$_{1-x}$La$_x$NiC$_2$ is discussed in the terms of the possible quantum critical point.

Editorial analysis

A structured set of objections, weighed in public.

Desk editor's note, referee report, simulated authors' rebuttal, and a circularity audit. Tearing a paper down is the easy half of reading it; the pith above is the substance, this is the friction.

Referee Report

1 major / 0 minor

Summary. The manuscript studies the doping series Nd_{1-x}La_xNiC_2 via structural, magnetic, transport, magnetoresistance and specific-heat measurements. It reports gradual suppression of the Peierls temperature TP(x) that is stated to follow the BCS mean-field relation for chemical pressure, fixing xc = 0.38 as the point of complete CDW suppression. While the CDW persists, the antiferromagnetic state remains robust (sharp transition despite falling TN); once the CDW is gone, AFM features soften with rising spin disorder, and superconductivity appears immediately after TN reaches zero. The sequence is interpreted as evidence for a quantum critical point separating the CDW-AFM and superconducting regimes.

Significance. If the phase boundaries are correctly located, the work would map a doping-driven crossover from CDW-stabilized antiferromagnetism to noncentrosymmetric superconductivity and supply an experimental example of a possible QCP in this family, which could inform models of competing orders.

major comments (1)
  1. [Abstract] Abstract (paragraph on TP suppression and xc = 0.38): the identification of the CDW suppression point rests on the unverified assumption that TP(x) obeys the BCS mean-field chemical-pressure scaling. No independent anchor (disappearance of superlattice peaks, specific-heat jump closure, or spectroscopic gap) is cited to confirm that CDW order actually terminates at this concentration. If La substitution modifies nesting or bandwidth beyond a pure volume effect, the demarcation between the 'CDW-present/AFM-robust' and 'CDW-absent/AFM-softening' regimes is misplaced, collapsing the claimed sequence and the QCP inference.

Simulated Author's Rebuttal

1 responses · 0 unresolved

We thank the referee for the careful reading of our manuscript and the constructive comment. We address the major point regarding the determination of the CDW suppression concentration below.

read point-by-point responses
  1. Referee: [Abstract] Abstract (paragraph on TP suppression and xc = 0.38): the identification of the CDW suppression point rests on the unverified assumption that TP(x) obeys the BCS mean-field chemical-pressure scaling. No independent anchor (disappearance of superlattice peaks, specific-heat jump closure, or spectroscopic gap) is cited to confirm that CDW order actually terminates at this concentration. If La substitution modifies nesting or bandwidth beyond a pure volume effect, the demarcation between the 'CDW-present/AFM-robust' and 'CDW-absent/AFM-softening' regimes is misplaced, collapsing the claimed sequence and the QCP inference.

    Authors: We appreciate the referee raising this issue about the robustness of xc = 0.38. In the full manuscript, TP(x) is determined from clear anomalies in the resistivity and magnetic susceptibility data, which decrease continuously with x. These data points are shown to be consistent with the BCS mean-field form expected for CDW suppression under chemical pressure, with the lattice volume changing linearly (from the structural refinements). This scaling is used to extrapolate the point at which TP reaches zero. While we do not claim direct spectroscopic confirmation of gap closure, the change in the character of the AFM transition and the onset of superconductivity occur in the vicinity of this extrapolated xc, lending support to the demarcation. We acknowledge that La substitution could in principle affect nesting beyond volume effects, though the smooth evolution of lattice parameters and the absence of abrupt changes in other properties argue against a strong deviation. To address the concern, we will revise the abstract to explicitly note that xc is obtained via extrapolation of the observed TP(x) using the mean-field relation, and we will add a brief discussion paragraph clarifying the assumption and its limitations. We will also note that future diffraction work could provide an independent check via superlattice peaks. revision: yes

Circularity Check

0 steps flagged

No circularity: experimental phase boundaries determined from direct measurements

full rationale

The manuscript reports a series of structural, magnetic, transport, magnetoresistance and specific-heat measurements on the Nd_{1-x}La_xNiC_2 doping series. The value xc = 0.38 is obtained by tracking the measured suppression of the Peierls temperature TP(x) and noting that the observed trend is consistent with the BCS mean-field form under chemical pressure; this is an external interpretive comparison, not an equation in which TP(x) or xc is defined in terms of itself or fitted to a subset of the same data and then re-used as a prediction. No self-citation chain, ansatz smuggling, or uniqueness theorem is invoked to close a loop. The central claims (AFM robustness while CDW persists, softening after CDW suppression, SC appearing after TN reaches zero) rest on the measured data points themselves rather than on any reduction to fitted inputs.

Axiom & Free-Parameter Ledger

1 free parameters · 0 axioms · 0 invented entities

The paper is an experimental doping study. The only free parameter extracted from the data is the critical concentration xc = 0.38. No new entities are postulated. Standard condensed-matter assumptions about mean-field behavior of the Peierls transition are invoked but not derived.

free parameters (1)
  • critical concentration xc = 0.38
    Value at which the Peierls temperature reaches zero, extracted from the doping dependence of the CDW transition.

pith-pipeline@v0.9.0 · 5774 in / 1324 out tokens · 26443 ms · 2026-05-25T14:14:44.577198+00:00 · methodology

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unclear
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Reference graph

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