REVIEW 2 major objections 4 minor 2 cited by
Thermopower across Fermi-volume-changing quantum phase transitions without translational symmetry breaking
T0 review · 2 major / 4 minor · reviewed 2026-08-11 · deepseek-v4-flash
Pith's one-line read Low-temperature thermopower across a Fermi-volume-changing quantum phase transition without translational symmetry breaking is large and asymmetric, matching experiments in CeRhIn5 and Nd-LSCO, and supporting a non-symmetry-breaking…
desk verdict A careful, honest large-N computation that turns the canonical boson's -iω term into a concrete, side-dependent thermopower asymmetry; the load-bearing caveat—purely random Kondo coupling, no uniform part—is the authors' own, and the experimental match stays qualitative. read the letter →
The pith
A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.
The reading
What carries the argument
The load-bearing object is the critical Higgs boson propagator $G_b(i\omega,\mathbf{k}) = 1/(-i\omega + \mathbf{k}^2/(2m_b) + \gamma|\omega| + \Delta_b(T))$, whose $-i\omega$ term comes from the boson being a canonical field carrying an emergent U(1) gauge charge; a symmetry-breaking order parameter would not have this term. This term generates the odd-in-frequency parts of the fermion scattering functions $g_\rho(x,z)$ in the self-energies, producing what the paper calls a 'skewed marginal Fermi liquid', following the framework in Ref. [19]. The Seebeck coefficient is assembled from the Onsager coefficients $L_0$ and $L_1$, with the electrical current vertices renormalized by the emergent gauge field (Ioffe-Larkin-type combination, Eq. (21)): the $f$-electron and boson channels add like resistors in series, the $c$-electron channel in parallel. The inversion between Kondo lattice and single-band models follows from which side of the transition has the condensed Higgs field.
What would settle it
An explicit large-N calculation that keeps both a uniform and a random Kondo coupling, $g+g'(r)$ with $g \gg g'$, would settle the claim: if the skewed-MFL thermopower asymmetry disappears or inverts once the uniform piece dominates, the proposed mechanism and the match to CeRhIn5 and Nd-LSCO would not survive. A second check is to search in CeRhIn5 for the predicted ultra-low-temperature super-logarithmic downturn of $S/T$ on the large-Fermi-surface side.
Extended reading notes
Core claim
The central claim is that the thermopower across a Fermi-volume-changing quantum phase transition without translational symmetry breaking is large and asymmetric because the critical boson is electrically charged. In the Kondo lattice model, the large-Fermi-surface FL phase has a condensed Higgs boson $b$, while the small-Fermi-surface FL* phase has a spin liquid with fractionalized excitations; the onset of the FL phase is the condensation of this Higgs field, which carries unit charge under an emergent U(1) gauge field. The boson propagator contains a linear-in-frequency term $-i\omega$, which is absent for symmetry-breaking order parameters, and this term makes the fermionic self-energies a 'skewed marginal Fermi liquid' with singular particle-hole asymmetry. As a result, $S/T$ is enhanced on the large-Fermi-surface side and has a non-monotonic downturn at low temperatures on the small-Fermi-surface side. In the ancilla description of single-band models the condensation is reversed, so the pseudogap FL* state has the condensed Higgs field and the thermopower enhancement sits on the pseudogap side. The paper shows this matches $S/T$ data across the pressure-tuned transition in CeRhIn5 and across the doping-tuned pseudogap critical point in Nd-LSCO, and it argues this supports a non-symmetry-breaking Fermi-volume-changing transition as the origin of the pseudogap at intermediate temperatures.
Load-bearing premise
The load-bearing premise is that the electron–Higgs interaction is purely random in space, so the translationally invariant Kondo coupling can be ignored for low-temperature thermoelectric transport; the paper explicitly calls this an unrealistic simplification that remains to be checked.
Editorial extensions
If this is right
- On the heavy-fermion side, the theory predicts an enhanced $S/T$ on the large-Fermi-surface side and a low-temperature non-monotonic downturn on the small-Fermi-surface side, as observed in CeRhIn5.
- On the cuprate side, the ancilla inversion predicts an enhanced thermopower on the pseudogap (small-Fermi-surface) side, matching Nd-LSCO and supporting a non-symmetry-breaking Fermi-volume-changing transition as the origin of the pseudogap.
- Thermopower becomes a diagnostic that can distinguish symmetry-breaking (weak, roughly symmetric) from non-symmetry-breaking (large, asymmetric) quantum phase transitions.
- The measured drop of the Hall coefficient across the pseudogap critical doping is consistent with the Fermi-volume change assumed here.
- The theory predicts that at sufficiently low temperature the large-Fermi-surface-side $S/T$ will eventually turn over and change sign, a feature not yet seen in Nd-LSCO data.
Reading between the lines
- If the uniform Kondo coupling is included and found to be subdominant, the same skewed-MFL mechanism should also produce a large asymmetric Nernst signal across the transition, since the Nernst effect couples to the same particle-hole asymmetry and critical boson dynamics.
- The inversion between Kondo lattice and single-band models suggests a practical classification: materials that show thermopower enhancement on their small-Fermi-surface side are consistent with the ancilla single-band description, while those with enhancement on the large-Fermi-surface side correspond to the two-band Kondo lattice picture.
- One could look for the same non-monotonic downturn in other heavy-fermion compounds with a Fermi-volume transition, where the temperature window for the skewed-MFL signal should be set by the elastic scattering rate.
- The theory implicitly predicts that thermopower, rather than resistivity, is the cleanest bulk probe of the pseudogap critical point, because the resistivity is dominated by the $c$-electrons while $S/T$ isolates the skewed channel; this could be tested by measuring $S/T$ anisotropy or thermal conductivity.
Editorial analysis
A structured set of objections, weighed in public.
Referee Report
Summary. This paper calculates the low-temperature thermopower in a Kondo lattice model across a Fermi-volume-changing quantum phase transition without translational symmetry breaking, using a large-N limit with spatially random Kondo exchange. The authors find a 'skewed' marginal Fermi liquid with a large, particle-hole asymmetric thermopower: the Seebeck coefficient is enhanced on the large-Fermi-surface side and non-monotonic on the small-Fermi-surface side. They compare these results with data on CeRhIn5 and, via the ancilla theory of single-band Hubbard models, with Nd-LSCO, concluding that the pseudogap onset in the cuprates is described by a non-symmetry-breaking Fermi-volume-changing transition. The computation is documented in appendices, and the paper explicitly identifies the purely random Kondo coupling as a simplifying assumption whose relaxation requires further work.
Significance. If the central result holds, the paper offers a concrete, falsifiable diagnostic: thermopower asymmetry and its temperature dependence can distinguish non-symmetry-breaking Fermi-volume-changing transitions from symmetry-breaking ones. The detailed large-N derivation, the explicit self-energy and Onsager-coefficient expressions, and the transparent comparison with two experimental systems are strengths. The calculation also makes a sharp prediction for the low-temperature downturn of S/T in the cuprate comparison. However, the significance is conditional on the assumed dominance of the purely random Kondo coupling over a uniform one, a point the authors themselves concede.
major comments (2)
- [Section IV and Eqs. (1), (4), (9), (31)] The central thermopower asymmetry is generated by the −iω term in the boson propagator (Eq. (4)) combined with the q-independent random Yukawa coupling g′(r) in Eq. (1). The paper concedes in Section IV that a translationally invariant Kondo coupling g is more realistic and that no calculation with g+g′(r) has been done. A uniform g typically produces a q-dependent Landau damping (of the form γ|ω|/|q| at small q), which does not reduce to the local γ|ω| used here. This would modify the skewed function g_ρ(x,z) in Eq. (9) and, in particular, the coefficient c_−(T) in Eq. (31) that controls the sign and non-monotonicity of S/T. Because the qualitative agreement with CeRhIn5 and Nd-LSCO depends on this coefficient, the claim should be presented as conditional on the validity of neglecting g, or supported by an explicit calculation.
- [Section IV and Fig. 5] The cuprate comparison is made in a restricted temperature window. The text states that the theoretical curves in Fig. 5(a) were 'cut off' at the smallest temperatures to illustrate the match, and that lower-temperature behavior would show a non-monotonicity 'absent in the experimental measurements.' Since the experimental data in Fig. 5(b) extends to low T without this feature, the agreement is not demonstrated in the full measured range. If the downturn is a prediction, the expected temperature scale should be given and the prediction shown; if the comparison is intended to be qualitative, this limitation should be stated in the abstract and conclusions.
minor comments (4)
- [Section III B and Fig. 4(a) caption] Section III B states Γf = 0.2, justified by ν_f/ν_c ≈ 10, but the Fig. 4(a) caption lists Γ_c = Γ_f = 0.02. Please clarify which value was used in the calculation and correct the inconsistency.
- [Section IV] There are typographical errors: 'translationaly' and 'illustate' should be 'translationally' and 'illustrate'.
- [Fig. 6 caption] The y-axis label 'c□' appears to be a rendering artifact; it should read c_−(T).
- [Section III B] A brief sensitivity analysis with respect to the chosen parameters (γ, Λ, m_b, Γ_c, Γ_f) would strengthen the claim that the qualitative features are not fine-tuned, especially because the experimental comparison is visual and qualitative.
Circularity Check
No significant circularity: the S/T calculation is self-contained, and the self-cited ancilla and random-Kondo frameworks are modeling inputs rather than fitted predictions.
full rationale
The thermopower derivation is self-contained: the model in Eq. (1), the large-N propagator Eq. (4), the self-energies Eqs. (7) and (9), and the Onsager transport formulas Eqs. (21)-(29) determine S/T without any use of the experimental thermopower data. The CeRhIn5 and Nd-LSCO comparisons in Figs. 4 and 5 are qualitative and are made after the calculation, not by fitting parameters to those data. The self-cited inputs, such as fractionalized Fermi liquids, the ancilla framework, and the random-Kondo model, are modeling assumptions with independent content; they do not enter as fitted parameters or as outputs recycled as predictions. The paper's own Section IV limitation, that only the purely random coupling g'(r) is retained while a uniform g is omitted, is a conceded assumption that makes the cuprate and heavy-fermion claims conditional, but it is not a circular reduction: no equation is defined in terms of the quantity it is said to predict, and the thermopower asymmetry is a computed consequence of the odd-in-omega term in Eq. (4), not a restatement of that term. No circular step meets the required evidence standard of exhibiting a specific reduction to an input.
Assumptions & free parameters
free parameters (7)
- Landau damping coefficient gamma =
0.05
- Boson UV cutoff Lambda =
100
- Boson mass mb =
25 (Kondo lattice), 5 (single band)
- Elastic scattering rate Gammac =
0.02
- Elastic scattering rate Gammaf =
0.2 (Kondo), 0.02 (single band)
- f-electron mass mf =
10 mc (Kondo), mc (single band)
- Tuning parameter offsets Delta kappa =
+/-0.003, -0.0015 (plotted)
assumptions (5)
- domain assumption The large-N saddle point controls the theory at physical spin degeneracy; 1/N corrections do not change the odd-in-frequency terms in the self-energy.
- domain assumption The hybridization boson b is canonical and carries an emergent U(1) charge, which gives the -iomega term with unit coefficient in the boson propagator (Eq. 4).
- ad hoc to paper Spatially random Kondo exchange is the dominant interaction; a uniform Kondo coupling g can be neglected for low-T thermoelectric transport.
- domain assumption Translational symmetry breaking is a secondary, lower-temperature phenomenon; the intermediate-temperature quantum-critical fan is governed only by the Fermi-volume-changing transition.
- ad hoc to paper The ancilla theory of the single-band Hubbard model has Gaussian fluctuation dynamics equivalent to the Kondo lattice model, with only the condensed-Higgs side inverted.
Cite this review
Pith. "Pith review of Thermopower across Fermi-volume-changing quantum phase transitions without translational symmetry breaking." pith.science (2026). https://pith.science/paper/CA46VF42
@misc{pith2026241215330,
author = {Pith},
title = {Pith review of: Thermopower across Fermi-volume-changing quantum phase transitions without translational symmetry breaking},
year = {2026},
howpublished = {\url{https://pith.science/paper/CA46VF42}},
note = {Machine review of arXiv:2412.15330}
}
read the original abstract
We describe the evolution of low-temperature thermopower across Fermi-volume-changing quantum phase transitions in Kondo lattice models without translational symmetry breaking. This transition moves from a heavy Fermi liquid with a conventional Luttinger-volume large Fermi surface to a 'FL*' state, characterized by a small Fermi surface and a spin liquid with fractionalized excitations. The onset of the large Fermi surface phase is driven by the condensation of a Higgs field that carries a unit gauge charge under an emergent U(1) gauge field. We consider the case with spatially random Kondo exchange, as this leads to strange metal behavior in electrical transport. We find a large asymmetric thermopower in a 'skewed' marginal Fermi liquid, with similarities to the skewed non-Fermi liquid of Georges and Mravlje (arXiv:2102.13224). Our findings are consistent with recent observations in heavy fermion compounds (Z.-Y. Cao et al., arXiv:2408.13604), and describe an enhancement of thermopower on the large Fermi surface side as well as a non-monotonic behavior on the small Fermi surface side. Our results also apply to single-band Hubbard models and the pseudogap transition in the cuprates. In the ancilla framework, single-band models exhibit an inverted Kondo lattice transition: the small Fermi surface pseudogap state corresponds to the condensed Higgs state. This inversion results in an enhancement of thermopower on the pseudogap side in our theory, consistent with observations in the cuprates (C. Collignon et al., arXiv:2011.14927; A. Gourgout et al., arXiv:2106.05959). We argue that these observations support a non-symmetry-breaking Fermi-volume-changing transition as the underlying description of the onset of the pseudogap in the cuprates.
Forward citations
Cited by 2 Pith papers
-
Lectures on insulating and conducting quantum spin liquids
The notes argue that the FL* state — small pockets plus a quantized spin-liquid anomaly — resolves the ADMR pocket and v_F >> v_Delta problems that defeated holon-metal and plain fermionic-parton theories of the cuprates.
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The foot, the fan, and the cuprate phase diagram: Fermi-volume-changing quantum phase transitions
The paper attributes the cuprate 'foot' to a disordered spin-density-wave transition and the 'fan' to a disorder-tuned FL-to-FL* Fermi-volume-changing transition described by a two-dimensional Yukawa-SYK model.
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hTYcagE2gtn/etUUwfn7ydA7E20=
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S. Chatterjee, S. Sachdev, and M. S. Scheurer, Intertwin- ing Topological Order and Broken Symmetry in a Theory 16 of Fluctuating Spin-Density Waves, Phys. Rev. Lett.119, 227002 (2017), arXiv:1705.06289 [cond-mat.str-el]
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M. S. Scheurer, S. Chatterjee, W. Wu, M. Ferrero, A. Georges, and S. Sachdev, Topological order in the pseudogap metal, Proc. Nat. Acad. Sci. 115, E3665 (2018), arXiv:1711.09925 [cond-mat.str-el]
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H. Shackleton and S. Zhang, Emergent polaronic cor- relations in doped spin liquids, arXiv e-prints (2024), arXiv:2408.02190 [cond-mat.str-el]
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T. M ¨uller, R. Thomale, S. Sachdev, and Y. Iqbal, Pola- ronic correlations from optimized ancilla wave functions for the Fermi-Hubbard model, arXiv e-prints (2024), arXiv:2408.01492 [cond-mat.str-el]
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M. Christos, Z.-X. Luo, H. Shackleton, Y.-H. Zhang, M. S. Scheurer, and S. Sachdev, A model ofd-wave super- conductivity, antiferromagnetism, and charge order on the square lattice, Proceedings of the National Academy of Science 120, e2302701120 (2023), arXiv:2302.07885 [cond-...
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M. Christos and S. Sachdev, Emergence of nodal Bogoli- ubov quasiparticles across the transition from the pseu- dogap metal to the d-wave superconductor, npj Quantum Materials 9, 4 (2024), arXiv:2308.03835 [cond-mat.str-el]
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M. Christos, H. Shackleton, S. Sachdev, and Z.-X. Luo, Deconfined quantum criticality of nodal d-wave super- conductivity, N´ eel order, and charge order on the square lattice at half-filling, Physical Review Research 6, 033018 (2024), arXiv:2402.09502 [cond-mat.str-el]
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P. M. Bonetti, M. Christos, and S. Sachdev, Quantum os- cillations in the hole-doped cuprates and the confinement of spinons, Proceedings of the National Academy of Sci- ences 121, e2418633121 (2024), arXiv:2405.08817 [cond- mat.str-el]
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J.-X. Zhang and S. Sachdev, Vortex structure in a d- wave superconductor obtained by a confinement transi- tion from the pseudogap metal, Phys. Rev. B 110, 235120 (2024), arXiv:2406.12964 [cond-mat.str-el]
2024 arXiv
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