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Multichannel Quantum Defect Theory for cold molecular collisions

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arxiv 1105.4483 v2 pith:DUEPOT5R submitted 2011-05-23 physics.atom-ph

classification physics.atom-ph
keywords calculationsdefectlow-energymolecularmqdtmultichannelquantumscattering
verification ladder T0 review T1 audit T2 compute T3 formal
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Multichannel Quantum Defect Theory (MQDT) is shown to be capable of producing quantitatively accurate results for low-energy atom-molecule scattering calculations. With a suitable choice of reference potential and short-range matching distance, it is possible to define a matrix that encapsulates the short-range collision dynamics and is only weakly dependent on energy and magnetic field. Once this has been produced, calculations at additional energies and fields can be performed at a computational cost that is proportional to the number of channels N and not to N^3. MQDT thus provides a promising method for carrying out low-energy molecular scattering calculations on systems where full exploration of the energy- and field-dependence is currently impractical.

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