A theoretical study of the C- 4So₃/2 and 2Do_(3/2,5/2) bound states and C ground configuration: fine and hyperfine structures, isotope shifts and transition probabilities
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⚛️ physics.atom-ph
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statesaccuracyhyperfineisotopeprobabilitiesshiftsstructurestransition
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This work is an ab initio study of the 2p3 4So_3/2, and 2Do_{3/2,5/2} states of C- and 2p2 3P_{0,1,2}, 1D_2, and 1S_0 states of neutral carbon. We use the multi-configuration Hartree-Fock approach, focusing on the accuracy of the wave function itself. We obtain all C- detachment thresholds, including correlation effects to about 0.5%. Isotope shifts and hyperfine structures are calculated. The achieved accuracy of the latter is of the order of 0.1 MHz. Intra-configuration transition probabilities are also estimated.
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