Energy level properties of 4p⁶4d³, 4p⁶4d²4f and 4p⁵4d⁴ configurations of W³⁵⁺ ion
classification
⚛️ physics.atom-ph
keywords
mathrmconfigurationseffectsenergyhartree-focklevelmethodquasirelativistic
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The ab initio quasirelativistic Hartree-Fock method developed specifically for the calculation of spectroscopic parameters of heavy atoms and highly charged ions was used to derive spectral data for the multicharged tungsten ion W$^{35+}$. The configuration interaction method was applied to include the electron-correlation effects. The relativistic effects were taken into account in the Breit-Pauli approximation for quasirelativistic Hartree-Fock radial orbitals. The energy level spectra, radiative lifetimes $\tau$, Lande $g$-factors are calculated for the $\mathrm{4p^64d^3}$, $\mathrm{4p^64d^24f}$ and $\mathrm{4p^54d^4}$ configurations of the W$^{35+}$ ion.
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