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arxiv: 0902.4605 · v1 · pith:JCW2UQOYnew · submitted 2009-02-26 · ❄️ cond-mat.str-el

Conserving quasiparticle calculations for small metal clusters

classification ❄️ cond-mat.str-el
keywords conservingcalculationsclustersobtainedquasiparticleresultsapplicationapproach
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A novel approach for GW-based calculations of quasiparticle properties for finite systems is presented, in which the screened interaction is obtained directly from a linear response calculation of the density-density correlation function. The conserving nature of our results is shown by explicit evaluation of the $f$-sum rule. As an application, energy renormalizations and level broadenings are calculated for the closed-shell Na$_9^+$ and Na$_{21}^+$ clusters, as well as for Na$_4$. Pronounced improvements of conserving approximations to RPA-level results are obtained.

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