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arxiv: 1603.07416 · v1 · pith:KKJK653Hnew · submitted 2016-03-24 · ⚛️ physics.atom-ph · physics.optics

Absolute frequency measurements and hyperfine structures of the molecular iodine transitions at 578 nm

classification ⚛️ physics.atom-ph physics.optics
keywords transitionsfrequencyhyperfineabsoluteiodinemeasuredmeasurementsmolecular
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We report absolute frequency measurements of 81 hyperfine components of the rovibrational transitions of molecular iodine at 578 nm using the second harmonic generation of an 1156-nm external-cavity diode laser and a fiber-based optical frequency comb. The relative uncertainties of the measured absolute frequencies are typically $1.4\times10^{-11}$. Accurate hyperfine constants of four rovibrational transitions are obtained by fitting the measured hyperfine splittings to a four-term effective Hamiltonian including the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions. The observed transitions can be good frequency references at 578 nm, and are especially useful for research using atomic ytterbium since the transitions are close to the $^{1}S_{0}-^{3}P_{0}$ clock transition of ytterbium.

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