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Spectroscopic characterization and detection of Ethyl Mercaptan in Orion
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abstract
New laboratory data of ethyl mercaptan, CH$_{3}$CH$_{2}$SH, in the millimeter and submillimeter-wave domains (up to 880 GHz) provided very precise values of the spectroscopic constants that allowed the detection of $gauche$-CH$_3$CH$_2$SH towards Orion KL. 77 unblended or slightly blended lines plus no missing transitions in the range 80-280 GHz support this identification. A detection of methyl mercaptan, CH$_{3}$SH, in the spectral survey of Orion KL is reported as well. Our column density results indicate that methyl mercaptan is $\simeq$ 5 times more abundant than ethyl mercaptan in the hot core of Orion KL.
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Cited by 1 Pith paper
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Binding energy distributions of alcohols, thiols, and their precursors on interstellar water ice surfaces
Quantum chemical binding energy distributions are reported for 16 O/S-bearing species on amorphous water ice, and using these distributions alters modeled ice-phase abundances.
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