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arxiv: 1201.3268 · v1 · pith:LPE2W2DEnew · submitted 2012-01-16 · ⚛️ physics.atom-ph

Resonances in rotationally inelastic scattering of OH(X²Pi) with helium and neon

classification ⚛️ physics.atom-ph
keywords scatteringresonancescrossemphinelasticradicalsrotationallysections
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We present detailed calculations on resonances in rotationally and spin-orbit inelastic scattering of OH ($X\,^2\Pi, j=3/2, F_1, f$) radicals with He and Ne atoms. We calculate new \emph{ab initio} potential energy surfaces for OH-He, and the cross sections derived from these surfaces compare favorably with the recent crossed beam scattering experiment of Kirste \emph{et al.} [Phys. Rev. A \textbf{82}, 042717 (2010)]. We identify both shape and Feshbach resonances in the integral and differential state-to-state scattering cross sections, and we discuss the prospects for experimentally observing scattering resonances using Stark decelerated beams of OH radicals.

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