Thermodynamic properties of quantum sine-Gordon spin chain system KCuGaF6

We investigated the thermodynamic properties of the spin-1/2 one-dimensional Heisenberg antiferromagnet KCuGaF6 by measuring the specific heat in magnetic fields. When this compound is subjected to a uniform magnetic field H a transverse staggered magnetic field h is induced in this compound owing to the staggered component of the g tensor and the Dzyaloshinskii-Moriya interaction with an alternating D vector. Consequently, the quantum sine-Gordon (SG) model is an effective model of this compound in a uniform magnetic field. In three different field directions, we observed a magnetic-field-induced gap, which increases with H. We analyzed experimental results using specific heat theory based on quantum SG theory. The thermodynamic property for H // c is very well described in terms of the elementary excitations characteristic of the quantum SG model, while for the other field directions, significant contributions from other excitation modes beyond the framework of the quantum SG model were observed. For H // b, a quantum phase transition between gapless and gapped ground states was observed.