Double-peaked Ca II traces a relativistic broad-line region disk in NGC 4593

Double-peaked emission lines are observed in a small percentage of active galactic nuclei (AGN). These lines allow the determination of properties of the line-emitting region, known as the broad-line region (BLR). We investigated the structure and kinematics of the BLR in the Seyfert galaxy NGC 4593 through an analysis of the NIR line blend of Ca II 8498, 8542, 8662, and O I 8446 observed in a 2019 VLT/MUSE spectrum. We performed a detailed decomposition of the near-infrared Ca II triplet and O I 8446 blend, extracting clean profiles of Ca II 8498, 8542, 8662 and O I 8446. We then fitted Ca 8662 with a relativistic elliptical line-emitting disk model. The line profiles are double-peaked with a FWHM of approx. 3700 km/s and exhibit a redward asymmetry with a red-to-blue peak ratio of 4:3. The Ca II triplet lines have an intensity ratio of 1:1:1 and show no evidence of a central narrow or intermediate-width component. The profiles of Ca II and O I are remarkably similar, suggesting a common region of origin. Given the 1:1:1 ratio of the Ca II triplet, this region is likely a high-density emission zone, and the Ca II 8662 profile is well described by a mildly eccentric, low-inclination relativistic disk with minimal internal turbulence. The profile represents one of the clearest kinematic signatures of a relativistic disk observed in BLR emission lines to date. The double-peaked profiles of the NIR Ca II triplet and O I 8446 in NGC 4593 represent the first detection of double-peaked Ca II and O I 8446 in a non-transient AGN spectrum. The minimal intrinsic turbulence (the lowest value reported for an AGN emission line to date) and absence of narrow or intermediate-width components in Ca II 8662 make it a powerful diagnostic tool of BLR structure and kinematics. Further investigations of the profiles of Ca II and O I in other AGN are recommended to better constrain BLR properties.