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arxiv: 1211.0925 · v1 · pith:QBSVX5P3new · submitted 2012-11-05 · 🧮 math.PR

A variational formula for the free energy of the partially directed polymer collapse

classification 🧮 math.PR
keywords collapseformulatransitionvariationaldirectedenergyfreeitself
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Long linear polymers in dilute solutions are known to undergo a collapse transition from a random coil (expand itself) to a compact ball (fold itself up) when the temperature is lowered, or the solvent quality deteriorates. A natural model for this phenomenon is a 1+1 dimensional self-interacting and partially directed self-avoiding walk. In this paper, we develop a new method to study the partition function of this model, from which we derive a variational formula for the free energy. This variational formula allows us to prove the existence of the collapse transition and to identify the critical temperature in a simple way. We also prove that the order of the collapse transition is 3/2.

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