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arxiv: 1404.1755 · v1 · pith:VU3MRU7Onew · submitted 2014-04-07 · ❄️ cond-mat.str-el

A hybrid vanadium fluoride with structurally isolated S = 1 kagome layers

classification ❄️ cond-mat.str-el
keywords compoundfluoridegroundkagomestatevanadiumantiferromagneticapproach
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A new organically-templated vanadium (III) fluoride, (NH4)2(C2H8N)[V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling within the ground state a pronounced change in magnetisation kinetics is observed.

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