CARS spectroscopy of the (v=0to1) band in rm{T₂}

Molecular hydrogen is a benchmark system for bound state quantum calculation and tests of quantum electrodynamical effects. While spectroscopic measurements on the stable species have progressively improved over the years, high resolution studies on the radioactive isotopologues $\rm{T_2}$, $\rm{HT}$ and $\rm{DT}$ have been limited. Here we present an accurate determination of $\rm{T_2}$ $Q(J = 0 - 5)$ transition energies in the fundamental vibrational band of the ground electronic state, by means of high resolution Coherent Anti-Stokes Raman Spectroscopy. With the present experimental uncertainty of $0.02\,\rm{cm^{-1}}$, which is a fivefold improvement over previous measurements, agreement with the latest theoretical calculations is demonstrated.