A spectroscopic study of the cycling transition 4s[3/2]₂-4p[5/2]₃ at 811.8 nm in Ar-39: Hyperfine structure and isotope shift

Doppler-free saturated absorption spectroscopy is performed on an enriched radioactive Ar-39 sample. The spectrum of the 3s^2 3p^5 4s [3/2]_2 - 3s^2 3p^5 4p [5/2]_3 cycling transition at 811.8 nm is recorded, and its isotope shift between Ar-39 and Ar-40 is derived. The hyperfine coupling constants A and B for both the 4s [3/2]_2 and 4p [5/2]_3 energy levels in Ar-39 are also determined. The results partially disagree with a recently published measurement of the same transition. Based on earlier measurements as well as the current work, the isotope shift and hyperfine structure of the corresponding transition in Ar-37 are also calculated. These spectroscopic data are essential for the realization of laser trapping and cooling of Ar-37 and Ar-39.