Hydrocarbon Dust Absorption in Seyfert Galaxies and ULIRGs

We present new spectroscopic observations of the 3.4 micron absorption feature in the Seyfert galaxies, NGC1068 and NGC7674, and the ultraluminous infrared galaxy, IRAS08572+3915. A signature of C-H bonds in aliphatic hydrocarbons, the 3.4 micron feature indicates the presence of organic material in Galactic and extragalactic dust. Here we compare the 3.4 micron feature in all the galaxies in which it has been detected. In several cases, the signal-to-noise ratio and spectral resolution permit a detailed examination of the feature profile, something which has rarely been attempted in extragalactic lines of sight. The 3.4 micron band in these galaxies closely resembles that seen in the Galactic diffuse ISM and in newly-formed dust in a protoplanetary nebula. The similarity implies a common carrier for the carbonaceous component of dust, and one which is resistant to processing in the interstellar and/or circumnuclear medium. We also examine the mid-IR spectrum of NGC1068, because absorption bands in the 5-8 micron region further constrain the chemistry of the 3.4 micron band carrier. While weak features like those present in the mid-IR spectrum of diffuse dust towards the Galactic center would be undetectable in NGC1068, the strong bands found in the spectra of many proposed dust analog materials are clearly absent, eliminating certain candidates and production mechanisms for the carrier. The absence of strong absorption features at 5-8 microns is also consistent with the interpretation that the similarity in the 3.4 micron feature in NGC1068 to that in Galactic lines of sight reflects real chemical similarity in the carbonaceous dust.