Local Ferromagnetism in Microporous Carbon with the Structural Regularity of Zeolite Y

Magnetization M(H,T) measurements have been performed on microporous carbon (MC) with a three-dimensional nano-array structure corresponding to that of a zeolite Y supercage. The obtained results unambiguously demonstrate the occurrence of high-temperature ferromagnetism in MC, probably originating from a topological disorder associated with curved graphene sheets. The results provide evidence that the ferromagnetic behavior of MC is governed by isolated clusters in a broad temperature range, and suggest the occurrence of percolative-type transition with the temperature lowering. A comparative analysis of the results obtained on MC and related materials is given.