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arxiv: cond-mat/0312059 · v1 · submitted 2003-12-02 · ❄️ cond-mat.str-el

Single Crystal Growth of Skutterudite CoP3 under High Pressure

classification ❄️ cond-mat.str-el
keywords cop3singlepressureundercrystalshighskutteruditeapparatus
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A new method to grow single crystals of skutterudite compounds is examined. Using a wedge-type, cubic-anvil, high-pressure apparatus, single crystals of CoP3 were grown from stoichiometric melts under a pressure of 3.5 GPa. Powder x-ray diffraction and electron probe microanalysis measurements indicate that the as-grown boules are a single phase of CoP3. The results suggest that CoP3 is a congruent melting compound under high pressure.

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