Theory of phonon-assisted "forbidden" optical transitions in spin-gapped systems

We consider the absorption of light with emission of one S(tot)=1 magnetic excitation in systems with a spin gap induced by quantum fluctuations. We argue that an electric dipole transition is allowed on the condition that a virtual phonon instantaneously breaks the inversion symmetry. We derive an effective operator for the transition and argue that the proposed theory explains the polarized experiments in CuGeO(3) and SrCu(2)[BO(3)](2).