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arxiv: cond-mat/0403459 · v2 · submitted 2004-03-18 · ❄️ cond-mat.str-el

Theory of optical spectral weights in Mott insulators with orbital degrees of freedom

classification ❄️ cond-mat.str-el
keywords opticalorbitalmultipletapproachcomplexcomponentscorrelatedcorrelations
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Introducing partial sum rules for the optical multiplet transitions, we outline a unified approach to magnetic and optical properties of strongly correlated transition metal oxides. On the example of LaVO$_3$ we demonstrate how the temperature and polarization dependences of different components of the optical multiplet are determined by the underlying spin and orbital correlations dictated by the low-energy superexchange Hamiltonian. Thereby the optical data provides deep insight into the complex spin-orbital physics and the role played by orbital fluctuations.

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