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arxiv: cond-mat/0612524 · v1 · submitted 2006-12-20 · ❄️ cond-mat.other

Confinement effects on the stimulated dissociation of molecular BECs

classification ❄️ cond-mat.other
keywords dissociationtrapcouplingmolecularreactionshapesizestimulated
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We show that a molecular BEC in a trap is stabilized against stimulated dissociation if the trap size is smaller than the resonance healing length $(\hbar^2/2mg\sqrt{n})^{1/2}$. The condensate shape determines the critical atom-molecule coupling frequency. We discuss an experiment for triggering dissociation by a sudden change of coupling or trap parameters. This effect demonstrates one of the unique collective features of 'superchemistry' in that the yield of a chemical reaction depends critically on the size and shape of the reaction vessel.

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