pith:3CDXWSYN
Corrosion Evolution of T91 Steel in Static Lead-Bismuth Eutectic Under an Oxidising Environment
T91 steel forms an iron-enriched BCC surface layer in oxidizing lead-bismuth eutectic, with oxide scale stability deciding whether corrosion stays intergranular or spreads.
arxiv:2602.19642 v3 · 2026-02-23 · cond-mat.mtrl-sci
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Claims
A stable, coherent oxide scale appears to be the deciding factor that controls whether intergranular LBE attack occurs or not. Most surprisingly, a layer of iron enriched body-centred cubic phase forms on the surface of LBE-corroded T91 at these conditions, contradicting previous studies, which reported only oxide-based surface layers.
That the observed iron-enriched BCC surface phase and the martensite decomposition slowing effect are intrinsic to the oxidizing LBE environment rather than artifacts of sample preparation, analysis technique, or limited test durations and temperatures.
T91 steel in oxidizing LBE shows grain-boundary corrosion that slows via localized Cr depletion and martensite decomposition, controlled by a coherent oxide scale, and develops an iron-enriched BCC surface phase contradicting prior oxide-only reports.
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Receipt and verification
| First computed | 2026-06-05T01:15:22.214191Z |
|---|---|
| Builder | pith-number-builder-2026-05-17-v1 |
| Signature | Pith Ed25519
(pith-v1-2026-05) · public key |
| Schema | pith-number/v1.0 |
Canonical hash
d8877b4b0df44359ef7b59c5ae3c90caf426722cdfd75727d9451eb045ffa54d
Aliases
· · · · ·Agent API
Verify this Pith Number yourself
curl -sH 'Accept: application/ld+json' https://pith.science/pith/3CDXWSYN6RBVT333LHC24PEQZL \
| jq -c '.canonical_record' \
| python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: d8877b4b0df44359ef7b59c5ae3c90caf426722cdfd75727d9451eb045ffa54d
Canonical record JSON
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