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pith:AVSKTUG5

pith:2026:AVSKTUG5AJVNPTMIDUNUJRS4FL
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Modeling the UV-photon irradiation of CS$_2$-bearing ices in the laboratory with the pyRate gas-grain astrochemical code. New insights into the missing sulfur problem

A. Fuente, A. Taillard, D. Navarro-Almaida, G.M. Mu\~noz Caro, O. Sipil\"a, R. Mart\'in-Dom\'enech, W. Riedel

Nondiffusive chemistry must be included to reproduce the sulfur-bearing species formed in UV-irradiated CO2:CS2 ices at 10 K.

arxiv:2605.03725 v1 · 2026-05-05 · astro-ph.GA

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\pithnumber{AVSKTUG5AJVNPTMIDUNUJRS4FL}

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Record completeness

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2 Internet Archive
3 Author claim open · sign in to claim
4 Citations open
5 Replications open
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The bundle contains the canonical record plus signed events. A mirror can host it anywhere and recompute the same current state with the deterministic merge algorithm.

Claims

C1strongest claim

The results indicate that nondiffusive chemistry is necessary to reproduce the formation of S-bearing species observed in the experiment.

C2weakest assumption

That the compiled chemical network contains all relevant reactions with sufficiently accurate barriers and that the experimental product identification and quantification are free of major systematic errors.

C3one line summary

The pyRate model requires nondiffusive chemistry to form observed S-bearing species in irradiated CO2:CS2 ice but overpredicts OCS, CS and SO while underpredicting SO2 and sulfur allotropes.

References

74 extracted · 74 resolved · 0 Pith anchors

[1] Ice origins of OCS and chemistry of CS _ 2 -bearing ice mantles. , keywords =. doi:10.1093/mnras/stae2345 , archivePrefix =. 2410.07736 , primaryClass = · doi:10.1093/mnras/stae2345
[2] Photoelectric heating of interstellar gas. , keywords =. doi:10.1086/190513 , adsurl = · doi:10.1086/190513
[3] T., Jin , M., Matis , K · doi:10.3847/1538-4365/ac3131
[4] Three-Phase Chemical Models of Dense Interstellar Clouds - Gas Dust Particle Mantles and Dust Particle Surfaces. , keywords =
[5] Measurements and simulations of rate coefficients for the deuterated forms of the H _ 2 ^ + + H _ 2 and H _ 3 ^ + + H _ 2 reactive systems at low temperature. , keywords =. doi:10.1051/0004-6361/20245 · doi:10.1051/0004-6361/202451757
Receipt and verification
First computed 2026-06-19T16:10:38.309201Z
Builder pith-number-builder-2026-05-17-v1
Signature Pith Ed25519 (pith-v1-2026-05) · public key
Schema pith-number/v1.0

Canonical hash

0564a9d0dd026ad7cd881d1b44c65c2ad055486a0b673bcda97546ca95cfd8de

Aliases

arxiv: 2605.03725 · arxiv_version: 2605.03725v1 · doi: 10.48550/arxiv.2605.03725 · pith_short_12: AVSKTUG5AJVN · pith_short_16: AVSKTUG5AJVNPTMI · pith_short_8: AVSKTUG5
Agent API
Verify this Pith Number yourself
curl -sH 'Accept: application/ld+json' https://pith.science/pith/AVSKTUG5AJVNPTMIDUNUJRS4FL \
  | jq -c '.canonical_record' \
  | python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: 0564a9d0dd026ad7cd881d1b44c65c2ad055486a0b673bcda97546ca95cfd8de
Canonical record JSON
{
  "metadata": {
    "abstract_canon_sha256": "8d27042055577bce987ef66ad1d56dac98319f09220cd3f9a4b756b8814c4925",
    "cross_cats_sorted": [],
    "license": "http://arxiv.org/licenses/nonexclusive-distrib/1.0/",
    "primary_cat": "astro-ph.GA",
    "submitted_at": "2026-05-05T13:11:04Z",
    "title_canon_sha256": "54877c1b69345c93e67c72b466155f4f66f2ed816712a15fc150e312c8156e92"
  },
  "schema_version": "1.0",
  "source": {
    "id": "2605.03725",
    "kind": "arxiv",
    "version": 1
  }
}