pith:KUIZDO5Y
Influence of solvent granularity on the effective interaction between charged colloidal suspensions
Explicit hard-sphere solvent in electrolyte simulations attracts counterions to nano-colloid surfaces via depletion and can reverse long-range forces from repulsive to attractive for divalent ions.
arxiv:cond-mat/0008391 v1 · 2000-08-27 · cond-mat.soft
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\pithnumber{KUIZDO5YN5QTQDHUXL7G6WQQTW}
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Record completeness
Claims
For divalent counterions and nano-sized colloids, hydration may lead to overscreened colloids with mutual attraction while the primitive model yields repulsive forces.
That the hard-sphere solvent plus primitive-model ions sufficiently capture real hydration and that the observed force reduction survives when the solvent is coarse-grained into the SPM.
Explicit solvent granularity renormalizes colloidal charges and induces hydration-driven attraction absent from the primitive model.
Formal links
Receipt and verification
| First computed | 2026-07-04T16:18:59.398368Z |
|---|---|
| Builder | pith-number-builder-2026-05-17-v1 |
| Signature | Pith Ed25519
(pith-v1-2026-05) · public key |
| Schema | pith-number/v1.0 |
Canonical hash
551191bbb86f61380cf4bafe6f5a109db03d26ff4706393f20fe1bddf6f3d847
Aliases
· · · · ·Agent API
Verify this Pith Number yourself
curl -sH 'Accept: application/ld+json' https://pith.science/pith/KUIZDO5YN5QTQDHUXL7G6WQQTW \
| jq -c '.canonical_record' \
| python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: 551191bbb86f61380cf4bafe6f5a109db03d26ff4706393f20fe1bddf6f3d847
Canonical record JSON
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"primary_cat": "cond-mat.soft",
"submitted_at": "2000-08-27T01:40:15Z",
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"source": {
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