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pith:NZPPNR4H

pith:2026:NZPPNR4HERNCSDQA7M4XWORMY7
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Single-Photon Double Ionization of Ozone

Andreas Hult Roos, Antoine Gloriod, Elias Gustafsson, Emelie Olsson, Gunnar Nyman, Gunnar \"Ohrwall, Ishita Kanungo, John H.D. Eland, John M. Dyke, Majdi Hochlaf, Nihar Ranjan Behera, Raimund Feifel, Richard J. Squibb, Saga Berglund, Simon G\"allblad, Veronica Daver Ideb\"ohn

Dissociative double ionization of ozone produces electronically excited cationic oxygen fragments in addition to ground-state ones.

arxiv:2605.10918 v1 · 2026-05-11 · physics.atm-clus · physics.chem-ph

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Record completeness

1 Bitcoin timestamp
2 Internet Archive
3 Author claim open · sign in to claim
4 Citations open
5 Replications open
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Claims

C1strongest claim

Our results demonstrate that dissociative double ionization of ozone produces electronically excited cationic atomic oxygen fragments in addition to the ground-state dissociation pathway, revealing a richer fragmentation dynamics than hitherto recognized.

C2weakest assumption

The assignment of experimental spectral features to specific dissociation channels depends on the accuracy of post-Hartree-Fock multi-configurational-interaction calculations for the dication potential energy surfaces and energetics.

C3one line summary

First single-photon double ionization spectrum of ozone shows dissociative pathways yielding electronically excited cationic oxygen fragments beyond the ground-state channel.

References

49 extracted · 49 resolved · 0 Pith anchors

[1] Calder, R., Shorttle, O., Jordan, S., Rimmer, P. & Constantinou, T. Abiotic ozone in the observable atmospheres of venus and venus-like exoplanets.Mon. Notices Royal Astron. Soc.540, 2432–2450 (2025) 2025
[2] Farman, J., Gardiner, B. & Shanklin, J. Large losses of total ozone in antarctica reveal seasonal clox/nox interaction. Nature315, 207–2010 (1985) 2010
[3] Kyoto protocol to the united nations framework convention on climate change 1997
[4] Mahla, S. & Mehnen, B. Photoionization dynamics of o2 and o3 for atmospheric and astrophysical applications.The J. Chem. Phys.163(2025) 2025
[5] Dyke, J., Golob, L., Jonathan, N., Morris, A. & Okuda, M. Vacuum ultraviolet photoelectron spectroscopy of transient species. part 4.—difluoromethylene and ozone.J. Chem. Soc. Faraday Transactions 2: 1974

Formal links

2 machine-checked theorem links

Receipt and verification
First computed 2026-05-18T14:11:50.880332Z
Builder pith-number-builder-2026-05-17-v1
Signature Pith Ed25519 (pith-v1-2026-05) · public key
Schema pith-number/v1.0

Canonical hash

6e5ef6c787245a290e00fb397b3a2cc7c959667848c818611bc98096373d3153

Aliases

arxiv: 2605.10918 · arxiv_version: 2605.10918v1 · doi: 10.48550/arxiv.2605.10918 · pith_short_12: NZPPNR4HERNC · pith_short_16: NZPPNR4HERNCSDQA · pith_short_8: NZPPNR4H
Agent API
Verify this Pith Number yourself
curl -sH 'Accept: application/ld+json' https://pith.science/pith/NZPPNR4HERNCSDQA7M4XWORMY7 \
  | jq -c '.canonical_record' \
  | python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: 6e5ef6c787245a290e00fb397b3a2cc7c959667848c818611bc98096373d3153
Canonical record JSON
{
  "metadata": {
    "abstract_canon_sha256": "424fdb609ea41f89c0ef1e649da4198179369996ba0a0cd638aab41ea55b8f49",
    "cross_cats_sorted": [
      "physics.chem-ph"
    ],
    "license": "http://arxiv.org/licenses/nonexclusive-distrib/1.0/",
    "primary_cat": "physics.atm-clus",
    "submitted_at": "2026-05-11T17:52:41Z",
    "title_canon_sha256": "d9373c14d572de5bbc021ebb7edfa534b60bf796f0a9158ce767d05da3ffb645"
  },
  "schema_version": "1.0",
  "source": {
    "id": "2605.10918",
    "kind": "arxiv",
    "version": 1
  }
}