pith:SLSNFM6L
Room Temperature Anisotropic Photoresponse in Low-Symmetry van der Waals Semiconductor CrPS$_4$
CrPS4 shows strong room-temperature linear dichroism reaching 60 in photocurrent with threefold axis dependence.
arxiv:2604.05572 v1 · 2026-04-07 · cond-mat.mes-hall · cond-mat.mtrl-sci
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Claims
Linearly polarized reflectivity and scanning photocurrent measurements in the 1.37-2.48 eV range reveal a robust dichroic response. The linear dichroism in reflection RLD reaches ~50, while in photocurrent PCLD it increases to ~60, with a sign reversal of the RLD between 1.6-1.8 eV... a 3-fold enhancement is obtained along the b-axis compared to the a-axis.
The anisotropic responses are attributed to the interaction between polarized light and Cr^{3+} d-orbital T1 and T2 transitions; this attribution is plausible but not directly proven by the measurements alone and could be affected by other contributions such as defects or substrate effects.
CrPS4 displays room-temperature linear dichroism reaching RLD ~50 and PCLD ~60 with sign reversal and 3-fold axis-dependent photocurrent enhancement arising from its crystal symmetry and Cr3+ orbital transitions.
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| First computed | 2026-05-20T00:00:37.715915Z |
|---|---|
| Builder | pith-number-builder-2026-05-17-v1 |
| Signature | Pith Ed25519
(pith-v1-2026-05) · public key |
| Schema | pith-number/v1.0 |
Canonical hash
92e4d2b3cb43683dc39b92abb06da48847824316dd7fab44b5a965f0eea81ce7
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Canonical record JSON
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