pith:SPCULJVA
Highly asymmetric electrolytes in the primitive model: Hypernetted chain solution in arbitrary spatial dimensions
A logarithmic-grid spectral solver extends hypernetted-chain calculations to ionic mixtures with size and charge ratios exceeding one thousand.
arxiv:1307.4200 v1 · 2013-07-16 · cond-mat.soft
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Record completeness
Claims
For three-dimensional fluids, ion size- and charge-ratios larger than one thousand can be treated, corresponding to hitherto computationally not accessed micrometer-sized colloidal spheres in 1-1 electrolyte.
The hypernetted-chain closure remains sufficiently accurate for the extreme asymmetries that the new solver can now reach; the abstract provides only moderate-asymmetry MD comparisons.
HNC approximation with logarithmic-grid Fourier-Bessel transforms yields pair correlations for primitive-model electrolytes at ion size- and charge-asymmetries larger than 1000 in any spatial dimension.
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Receipt and verification
| First computed | 2026-05-18T02:55:27.596828Z |
|---|---|
| Builder | pith-number-builder-2026-05-17-v1 |
| Signature | Pith Ed25519
(pith-v1-2026-05) · public key |
| Schema | pith-number/v1.0 |
Canonical hash
93c545a6a04749baf43f837e634e3aef6ede495021ed729d1bf21ac49ace4deb
Aliases
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Verify this Pith Number yourself
curl -sH 'Accept: application/ld+json' https://pith.science/pith/SPCULJVAI5E3V5B7QN7GGTR255 \
| jq -c '.canonical_record' \
| python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: 93c545a6a04749baf43f837e634e3aef6ede495021ed729d1bf21ac49ace4deb
Canonical record JSON
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