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pith:2026:XJDUSOFCWFZW5XCX5IFJIZUUC3
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Magnetocaloric Effect in Nanostructured $La_{0.6}Sr_{0.4}Fe_{1-x}Co_{x}O_3$

Fabiana N. Morales Alvarez, Joaqu\'in Sacanell, Mariano Quintero

Cobalt substitution combined with nanostructuring maximizes magnetocaloric entropy change to 1.13 J/kg K under 3 T in La0.6Sr0.4Fe1-xCoxO3.

arxiv:2605.13611 v1 · 2026-05-13 · cond-mat.mtrl-sci

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Claims

C1strongest claim

These results demonstrate that the combination of Co doping and controlled nanostructuring effectively optimizes the magnetocaloric response, with a maximum entropy change of 1.13 J/(kg K) under 3 T for x=1.

C2weakest assumption

That the Maxwell relations applied to the measured magnetization curves give an accurate entropy change without significant contributions from particle-size effects or undetected secondary phases in the nanostructured samples.

C3one line summary

Cobalt substitution in these nanostructured perovskites increases ferromagnetic coupling and produces a maximum magnetic entropy change of 1.13 J/kg K under 3 T for the x=1 composition.

References

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[1] The MCE is defined as the isothermal change in magnetic entropy (−ΔS) that occurs when a magnetic field is applied to a material
[2] Experimental Nanostructured La0.6Sr0.4Fe1-xCoxO3 (x = 0, 0.2, 0.5, 0.8 and 1) samples were prepared by the pore-wetting technique, following the methodology previously reported for La0.6Sr0.4CoO3 pero
[3] Results and discussion 40 60 80 30 40 50 60 70 80 90 x = 0 2 1 40 2 42 0 2 1 1 0 1 0 4 d = 800 nm x = 0 d = 200 nm x = 0.2 x = 0.2 Intensity (a.u) x = 0.5 x = 0.5 x = 0.8 x = 0.8 x = 1 2(°) x = 1 Fi
[4] A clear dependence of magnetization on cobalt content is observed
[5] exhibit smaller slopes (on the order of 10-8–10-10 emu g⁻¹ Oe-1), consistent with a more ideal mean-field-like behavior. In contrast, compositions with lower Co content (x = 0.2 – 0.5) show larger slo 2000
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First computed 2026-05-18T02:44:18.050309Z
Builder pith-number-builder-2026-05-17-v1
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ba474938a2b1736edc57ea0a94669416f346b351812f7a4453f817d502f49fe5

Aliases

arxiv: 2605.13611 · arxiv_version: 2605.13611v1 · doi: 10.48550/arxiv.2605.13611 · pith_short_12: XJDUSOFCWFZW · pith_short_16: XJDUSOFCWFZW5XCX · pith_short_8: XJDUSOFC
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Canonical record JSON
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    "primary_cat": "cond-mat.mtrl-sci",
    "submitted_at": "2026-05-13T14:43:52Z",
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