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fragilityMax
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IndisputableMonolith.Chemistry.GlassTransition on GitHub at line 98.
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95def fragilityMin : ℝ := 16
96
97/-- Upper bound on fragility index (polymer-like). -/
98def fragilityMax : ℝ := 200
99
100/-- Strong glass fragility range. -/
101def isStrongGlass (m : ℝ) : Prop := fragilityMin ≤ m ∧ m ≤ 30
102
103/-- Fragile glass fragility range. -/
104def isFragileGlass (m : ℝ) : Prop := 100 ≤ m ∧ m ≤ fragilityMax
105
106/-! ## φ-Scaling of Relaxation Time
107
108The relaxation time τ scales as:
109 τ = τ₀ × φ^n
110
111where n depends on temperature relative to Tg.
112-/
113
114/-- Relaxation time scaling with φ. -/
115def relaxationTime (τ₀ : ℝ) (n : ℕ) : ℝ := τ₀ * Constants.phi ^ n
116
117/-- Relaxation time is positive. -/
118theorem relaxation_pos (τ₀ : ℝ) (hτ : 0 < τ₀) (n : ℕ) :
119 0 < relaxationTime τ₀ n := by
120 dsimp [relaxationTime]
121 apply mul_pos hτ
122 exact pow_pos Constants.phi_pos n
123
124/-! ## Falsification Criteria
125
126The glass transition derivation is falsifiable:
127
1281. **Kauzmann ratio**: If Tg/Tm deviates significantly from 2/3