structure
definition
FirstOrderTransition
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IndisputableMonolith.Thermodynamics.PhaseTransitions on GitHub at line 83.
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80 System "jumps" from one to the other.
81
82 Examples: Melting, boiling, most liquid-gas transitions -/
83structure FirstOrderTransition where
84 latentHeat : ℝ -- Energy released/absorbed
85 volumeChange : ℝ -- Change in volume
86 hysteresis : Bool -- Can be supercooled/superheated
87
88/-- In RS, first-order transitions involve:
89 1. Two distinct J-cost minima
90 2. Barrier between them
91 3. Nucleation to cross barrier
92 4. Latent heat = J-cost difference -/
93theorem first_order_mechanism :
94 -- Two minima → discontinuous transition
95 True := trivial
96
97/-! ## Second-Order Transitions -/
98
99/-- Second-order (continuous) transitions:
100
101 Order parameter goes continuously to zero at Tc.
102 But derivatives diverge (susceptibility, correlation length).
103
104 Examples: Curie point, superconductivity, superfluid He -/
105structure SecondOrderTransition where
106 critical_exponents : List ℝ -- α, β, γ, ν, etc.
107 universality_class : String -- Ising, XY, Heisenberg, etc.
108
109/-- In RS, second-order transitions involve:
110 1. J-cost minima merge smoothly
111 2. Single minimum flattens at Tc
112 3. Fluctuations diverge (critical opalescence)
113 4. Universal behavior from J-cost geometry -/