Perturbation theory gives a universal quadrupolar shape correction σ₂(κa) to electrophoretic mobility that is 1/5 in the Hückel limit and zero in the Smoluchowski limit.
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Shape-dependence of electrophoretic mobility
Perturbation theory gives a universal quadrupolar shape correction σ₂(κa) to electrophoretic mobility that is 1/5 in the Hückel limit and zero in the Smoluchowski limit.