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Geometric Analysis of Variational Quantum Eigensolver

1 Pith paper cite this work. Polarity classification is still indexing.

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abstract

The Variational Quantum Eigensolver (VQE) is a fundamental algorithm in quantum computing, yet a coherent geometric characterization of VQE remains missing due to fragmented analyses across fixed-ansatz and adaptive-circuit formulations. In this paper, we establish a geometric analysis of VQE in terms of optimization landscape, initialization guarantee, and noise robustness. First, we study the optimization landscape via an ansatz-free product-unitary formulation over the unitary group, unifying both paradigms. For the single-unitary case, we establish linear convergence of Riemannian gradient descent (RGD) and prove the strict saddle property. For the product-unitary case, we show the convergence rate deteriorates polynomially with circuit depth, providing a geometric explanation of the barren plateau phenomenon. Second, we prove that small-angle random Pauli-rotation circuits satisfy the required initialization conditions with high probability. Third, we show that RGD retains linear convergence under finite-shot measurements, and that coefficient-adaptive allocation achieves strictly lower statistical error than uniform sampling under a fixed measurement budget.

years

2026 1

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UNVERDICTED 1

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A Givens-exchange ansatz for molecular variational eigensolvers

physics.chem-ph · 2026-06-25 · unverdicted · novelty 6.0

A fixed Givens-exchange ansatz with two ordered all-pair blocks and RY rotations achieves six-seed mean errors of 0.000000124, 0.000128558, and 0.000002152 Hartree on LiH-6, H2O-8, and BeH2-6 Hamiltonians respectively, all chemically accurate.

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  • A Givens-exchange ansatz for molecular variational eigensolvers physics.chem-ph · 2026-06-25 · unverdicted · none · ref 29 · internal anchor

    A fixed Givens-exchange ansatz with two ordered all-pair blocks and RY rotations achieves six-seed mean errors of 0.000000124, 0.000128558, and 0.000002152 Hartree on LiH-6, H2O-8, and BeH2-6 Hamiltonians respectively, all chemically accurate.