A fixed Givens-exchange ansatz with two ordered all-pair blocks and RY rotations achieves six-seed mean errors of 0.000000124, 0.000128558, and 0.000002152 Hartree on LiH-6, H2O-8, and BeH2-6 Hamiltonians respectively, all chemically accurate.
Geometric Analysis of Variational Quantum Eigensolver
1 Pith paper cite this work. Polarity classification is still indexing.
abstract
The Variational Quantum Eigensolver (VQE) is a fundamental algorithm in quantum computing, yet a coherent geometric characterization of VQE remains missing due to fragmented analyses across fixed-ansatz and adaptive-circuit formulations. In this paper, we establish a geometric analysis of VQE in terms of optimization landscape, initialization guarantee, and noise robustness. First, we study the optimization landscape via an ansatz-free product-unitary formulation over the unitary group, unifying both paradigms. For the single-unitary case, we establish linear convergence of Riemannian gradient descent (RGD) and prove the strict saddle property. For the product-unitary case, we show the convergence rate deteriorates polynomially with circuit depth, providing a geometric explanation of the barren plateau phenomenon. Second, we prove that small-angle random Pauli-rotation circuits satisfy the required initialization conditions with high probability. Third, we show that RGD retains linear convergence under finite-shot measurements, and that coefficient-adaptive allocation achieves strictly lower statistical error than uniform sampling under a fixed measurement budget.
fields
physics.chem-ph 1years
2026 1verdicts
UNVERDICTED 1representative citing papers
citing papers explorer
-
A Givens-exchange ansatz for molecular variational eigensolvers
A fixed Givens-exchange ansatz with two ordered all-pair blocks and RY rotations achieves six-seed mean errors of 0.000000124, 0.000128558, and 0.000002152 Hartree on LiH-6, H2O-8, and BeH2-6 Hamiltonians respectively, all chemically accurate.