FDTD simulations show metal interfaces and cavities modify Raman signals via local field changes, relaxation-induced broadening, and interference effects including Rabi contraction comparable in strength to the Raman signal itself.
Surface-enhanced raman spectroscopy,
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Raman spectroscopy at metal interfaces: A numerical study of the strong coupling regime
FDTD simulations show metal interfaces and cavities modify Raman signals via local field changes, relaxation-induced broadening, and interference effects including Rabi contraction comparable in strength to the Raman signal itself.