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Thermodynamic and structural behavior of one-dimensional divalent patchy hard rods: Wertheim's first-order thermodynamic perturbation theory versus exact results

cond-mat.soft · 2026-05-20 · unverdicted · novelty 6.0

Wertheim TPT1 is rendered exact in 1D for divalent patchy rods via exact density-unbonded fraction relations and bonding free energy, revealing monotonic-to-oscillatory pair-correlation decay separated by a Fisher-Widom line plus Widom and ECO lines that vanish in the sticky limit.

On the correlation lengths of confined spheres in a cylindrical pore

cond-mat.soft · 2026-06-07 · unverdicted · novelty 5.0

Transverse-resolved RDFs in quasi-1D confined hard spheres can be governed by different leading poles than the global RDF, yielding distinct correlation lengths and frequencies that depend on transverse configuration and density.

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