In the freely jointed chain, fluctuations in extension and angles stay large at moderate forces but decrease with more links except for independent link angles.
Grasinger, Polymer networks which locally rotate to accommodate stresses, torques, and deformation, Jour- nal of the Mechanics and Physics of Solids175, 105289 (2023)
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Thermodynamic fluctuations in freely jointed chains under force
In the freely jointed chain, fluctuations in extension and angles stay large at moderate forces but decrease with more links except for independent link angles.