RIXS measurements and cluster calculations determine opposite trigonal distortions in VBr3 (-0.096 eV) and VI3 (0.07 eV), yielding distinct high-spin V3+ ground states.
Trigonal symmetry breaking and its elec- tronic effects in the two-dimensional dihalides MX 2 and trihalides MX3.Physical Review B, 105(24):245153
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Trigonal Distortion Driven Ground States in VX3 (X = Br and I)
RIXS measurements and cluster calculations determine opposite trigonal distortions in VBr3 (-0.096 eV) and VI3 (0.07 eV), yielding distinct high-spin V3+ ground states.