Cu-deficient crystals show extensive stacking faults tied to chemical inhomogeneity while Cu-rich crystals exhibit precipitates and fewer faults, with DFT indicating greater polarity in the Cu-rich case.
(21) Huang, F .-T.; Xue, F .; Gao, B.; Wang, L
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Impact of Cu-Mn ratio on Structure and Defects in Layered Multiferroic Cu1-xMn1+ySiTe3
Cu-deficient crystals show extensive stacking faults tied to chemical inhomogeneity while Cu-rich crystals exhibit precipitates and fewer faults, with DFT indicating greater polarity in the Cu-rich case.