Ethylbenzene dehydrogenation on rutile TiO2(110) proceeds via PCET on stoichiometric surfaces but shifts to HAT on oxidized surfaces, with 257 nm light bypassing ground-state barriers by persisting in excited states while 343 nm does not.
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A Theoretical Investigation of the Thermal and Photochemical Mechanisms of Ethylbenzene Dehydrogenation on Rutile TiO$_{2}$(110)
Ethylbenzene dehydrogenation on rutile TiO2(110) proceeds via PCET on stoichiometric surfaces but shifts to HAT on oxidized surfaces, with 257 nm light bypassing ground-state barriers by persisting in excited states while 343 nm does not.