For a pair of two-level molecules, semiclassical Ehrenfest dynamics with a fully correlated Hamiltonian (#I-FCI) overestimates long-time electronic energy under driving, while simpler mean-field or truncated methods do not.
(6), and|ψhe(t)⟩ char- acterizes the wave function for higher excitations
1 Pith paper cite this work. Polarity classification is still indexing.
1
Pith paper citing it
fields
physics.chem-ph 1years
2019 1verdicts
CONDITIONAL 1representative citing papers
citing papers explorer
-
Understanding the Nature of Mean-Field Semiclassical Light-Matter Dynamics: An Investigation of Energy Transfer, Electron-Electron Correlations, External Driving and Long-Time Detailed Balance
For a pair of two-level molecules, semiclassical Ehrenfest dynamics with a fully correlated Hamiltonian (#I-FCI) overestimates long-time electronic energy under driving, while simpler mean-field or truncated methods do not.