In C2v symmetry, carbene addition to and elimination from three-membered C/Si rings follow different diabatic pathways with no saddle point, while in Cs symmetry they merge into a single adiabatic path.
West , author M
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Chemical bonding in three-membered ring systems
In C2v symmetry, carbene addition to and elimination from three-membered C/Si rings follow different diabatic pathways with no saddle point, while in Cs symmetry they merge into a single adiabatic path.