Larger hard spheres in spherical confinement are entropically driven to and trapped at the vertices of icosahedral clusters formed by smaller spheres.
Phase behaviour of hard spheres confined between parallel hard plates: manip- ulation of colloidal crystal structures by confinement
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Entropic Trapping of Hard Spheres in Spherical Confinement
Larger hard spheres in spherical confinement are entropically driven to and trapped at the vertices of icosahedral clusters formed by smaller spheres.