Indirect 5d-mediated exchange dominates in CsCeSe2, superexchange dominates in RbCeO2, and both contribute equally in KCeS2, with calculated spin Hamiltonians yielding magnetic excitation spectra in good agreement with experiment.
Title resolution pending
2 Pith papers cite this work. Polarity classification is still indexing.
2
Pith papers citing it
representative citing papers
Isostructural CeCN5 and TbCN5 show Ce in 4+ and Tb in 3+ oxidation states, producing insulating versus metallic behavior because the polymeric C-N network distributes the extra electron from Ce.
citing papers explorer
-
5d-mediated indirect exchange and effective spin Hamiltonians in Ce triangular-lattice delafossites
Indirect 5d-mediated exchange dominates in CsCeSe2, superexchange dominates in RbCeO2, and both contribute equally in KCeS2, with calculated spin Hamiltonians yielding magnetic excitation spectra in good agreement with experiment.
-
Electronic structure and oxidation states in high-pressure synthesized isostructural CeCN$_5$ and TbCN$_5$
Isostructural CeCN5 and TbCN5 show Ce in 4+ and Tb in 3+ oxidation states, producing insulating versus metallic behavior because the polymeric C-N network distributes the extra electron from Ce.