Hyperfine interaction splits each Stark state by the ion-core Fermi-contact splitting while molecular rotation induces Stark-state-specific splittings that differ from the core spin-rotation splitting.
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Algorithm for eigenvalues of generalized spheroidal wave equations that constructs analytic derivatives as three-term recurrences within the continued-fraction method and demonstrates it on quasimolecular systems including H2+ at large separations.
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The Stark effect in molecular Rydberg states: Calculation of Rydberg-Stark manifolds of H$_2$ and D$_2$ including fine and hyperfine structures
Hyperfine interaction splits each Stark state by the ion-core Fermi-contact splitting while molecular rotation induces Stark-state-specific splittings that differ from the core spin-rotation splitting.
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Generalized spheroidal wave equation for real and complex valued parameters. An algorithm based on the analytic derivatives for the eigenvalues
Algorithm for eigenvalues of generalized spheroidal wave equations that constructs analytic derivatives as three-term recurrences within the continued-fraction method and demonstrates it on quasimolecular systems including H2+ at large separations.