Pumping the upper polariton of liquid methane can transiently excite the IR-inactive symmetric bending mode, and the effect is strongest when the polariton is two-thirds photonic in character.
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Selective Excitation of IR-Inactive Modes via Vibrational Polaritons: Insights from Atomistic Simulations
Pumping the upper polariton of liquid methane can transiently excite the IR-inactive symmetric bending mode, and the effect is strongest when the polariton is two-thirds photonic in character.