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From Quantum Chaos and Eigenstate Thermalization to Statistical Mechanics and Thermodynamics

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This review gives a pedagogical introduction to the eigenstate thermalization hypothesis (ETH), its basis, and its implications to statistical mechanics and thermodynamics. In the first part, ETH is introduced as a natural extension of ideas from quantum chaos and random matrix theory (RMT). To this end, we present a brief overview of classical and quantum chaos, as well as RMT and some of its most important predictions. The latter include the statistics of energy levels, eigenstate components, and matrix elements of observables. Building on these, we introduce the ETH and show that it allows one to describe thermalization in isolated chaotic systems without invoking the notion of an external bath. We examine numerical evidence of eigenstate thermalization from studies of many-body lattice systems. We also introduce the concept of a quench as a means of taking isolated systems out of equilibrium, and discuss results of numerical experiments on quantum quenches. The second part of the review explores the implications of quantum chaos and ETH to thermodynamics. Basic thermodynamic relations are derived, including the second law of thermodynamics, the fundamental thermodynamic relation, fluctuation theorems, and the Einstein and Onsager relations. In particular, it is shown that quantum chaos allows one to prove these relations for individual Hamiltonian eigenstates and thus extend them to arbitrary stationary statistical ensembles. We then show how one can use these relations to obtain nontrivial universal energy distributions in continuously driven systems. At the end of the review, we briefly discuss the relaxation dynamics and description after relaxation of integrable quantum systems, for which ETH is violated. We introduce the concept of the generalized Gibbs ensemble, and discuss its connection with ideas of prethermalization in weakly interacting systems.

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representative citing papers

Local Strong-to-Weak Spontaneous Symmetry Breaking

quant-ph · 2026-05-27 · unverdicted · novelty 7.0

Introduces a local one-point fidelity correlator to define SW-SSB, preserving key features like channel stability and long-range conditional mutual information while enabling detection in large and thermodynamic-limit systems.

Bouncing singularities and thermal correlators on line defects

hep-th · 2026-03-11 · accept · novelty 7.0

Retarded correlators of bulk scalars and Wilson-line displacement operators exhibit bouncing singularities at t_c=β/2(1+i) with matching WKB and asymptotic OPE data, implying a universal high-frequency factorization.

Hilbert Space Fragmentation from Generalized Symmetries

hep-lat · 2026-04-14 · unverdicted · novelty 7.0

Generalized symmetries generate exponentially many Krylov sectors in quantum many-body systems, showing that Hilbert space fragmentation does not by itself imply ergodicity breaking.

A superintegrable quantum field theory

nlin.SI · 2025-11-05 · unverdicted · novelty 6.0

The quantum cubic Szegő equation exhibits integer spectra for its Hamiltonian and conserved hierarchies, indicating superintegrability beyond ordinary quantum integrability.

Localized Fock Space Cages in Kinetically Constrained Models

quant-ph · 2025-04-29 · unverdicted · novelty 6.0

Fock space cages from destructive interference in kinetically constrained models yield localized many-body eigenstates and non-ergodic dynamics by treating Fock space as a graph of bitstring states.

Locality versus Fock-space structure in East-type models

cond-mat.dis-nn · 2026-04-30 · unverdicted · novelty 6.0

Randomizing Fock-space connections in the quantum East model preserves the localization transition, showing that Fock-space graph structure matters more than geometric locality.

Hilbert Space Fragmentation and Gauge Symmetry

hep-lat · 2026-04-17 · unverdicted · novelty 6.0

An emergent gauge symmetry valid only in a subset of sectors of the fragmented S=1 dipole-conserving spin chain enables exact quantum simulation of gauge theories using a non-gauge-invariant Hamiltonian.

Thermalization with Gaussian Quantum Cellular Automata

math-ph · 2026-06-04 · unverdicted · novelty 5.0

Provides two sets of conditions on GQCAs guaranteeing thermalization to infinite temperature via a quantum many-body generalization of the Riemann-Lebesgue lemma for states with bounded density.

Generic ETH: Eigenstate Thermalization beyond the Microcanonical

quant-ph · 2024-03-08 · unverdicted · novelty 5.0

Numerical study of a qutrit lattice with conserved charge shows thermalization signatures in states outside microcanonical windows of energy and charge, supporting a generalized form of ETH called generic ETH.

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