Varying assumed metallicity, C/O, S/N, and 1-bar temperature in thermochemical equilibrium models changes predicted mixing ratios and cloud decks of Uranus and Neptune by more than an order of magnitude, and thermal profiles by tens of kelvins.
The measured compositions of Uranus and Neptune from their formation on the CO iceline
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abstract
The formation mechanisms of the ice giants Uranus and Neptune, and the origin of their elemental and isotopic compositions, have long been debated. The density of solids in the outer protosolar nebula is too low to explain their formation, and spectroscopic observations show that both planets are highly enriched in carbon, very poor in nitrogen, and the ices from which they originally formed might had deuterium-to-hydrogen ratios lower than the predicted cometary value, unexplained properties observed in no other planets. Here we show that all these properties can be explained naturally if Uranus and Neptune both formed at the carbon monoxide iceline. Due to the diffusive redistribution of vapors, this outer region of the protosolar nebula intrinsically has enough surface density to form both planets from carbon-rich solids but nitrogen-depleted gas, in abundances consistent with their observed values. Water rich interiors originating mostly from transformed CO ices reconcile the D/H value of Uranus and Neptune's building blocks with the cometary value. Finally, Our scenario generalizes a well known hypothesis that Jupiter formed on an iceline (water snowline) for the two ice giants, and might be a first step towards generalizing this mechanism for other giant planets.
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The atmospheric vertical structure of Uranus and Neptune from thermochemical models: the impact of model assumptions
Varying assumed metallicity, C/O, S/N, and 1-bar temperature in thermochemical equilibrium models changes predicted mixing ratios and cloud decks of Uranus and Neptune by more than an order of magnitude, and thermal profiles by tens of kelvins.