An analytic theory for cosolvency in polymer brushes derives a concentration-dependent interaction parameter from preferential adsorption, predicting discontinuous swelling followed by re-collapse without requiring bulk solvent repulsion.
Semenov, Contribution to the theory of microphase layering in block -copolymer melts, Soviet Physics JETP, 61 (1985) 733-742
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Cosolvency response in polymer brushes
An analytic theory for cosolvency in polymer brushes derives a concentration-dependent interaction parameter from preferential adsorption, predicting discontinuous swelling followed by re-collapse without requiring bulk solvent repulsion.